From Frustrated Packing to Tecton-Driven Porous Molecular Solids

Porous Molecular Solids and Liquids

Until recently, porous molecular solids were isolated curiosities with properties that were eclipsed by porous frameworks, such as metal-organic frameworks. Now molecules have emerged as a functional materials platform that can have high levels of porosity, good chemical stability, and, uniquely, solution processability. The lack of intermolecular bonding in these materials has also led to new,...

Perspective: THz-driven nuclear dynamics from solids to molecules

Recent years have seen dramatic developments in the technology of intense pulsed light sources in the THz frequency range. Since many dipole-active excitations in solids and molecules also lie in this range, there is now a tremendous potential to use these light sources to study linear and nonlinear dynamics in such systems. While several experimental investigations of THz-driven dynamics in so...

Author’s Reply to “A Note on the Simulation of Gas Diffusion in Capillaries and Porous Solids”

Synthesis of nano-porous molecular sieve from some natural materials

Zeolites due to their structures can be used as molecular sieves for purification of materials and solutions. Zeolites with PHI and SOD structure are so common and applicable for this purpose. Hydroxy sodalite and phillipsite are the more abundant members of zeolites which display good selectivity for very small molecules and some ions such as Sr, Pb, Zn, Cu and Rb. There is not any pure natura...

Rigidity-based approach to the boson peak in amorphous solids: from sphere packing to amorphous silica

Glasses have a large excess of low-frequency vibrational modes in comparison with continuous elastic body, the so-called Boson Peak, which appears to correlate with several crucial properties of glasses, such as transport or fragility. I review recent results showing that the Boson Peak is a necessary consequence of the weak connectivity of the solid. I explain why in assemblies repulsive spher...